Holt McDougal Chemistry Chapter 4

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Waves and Particles

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Waves and Particles

Light has characteristics of these two things.

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Electromagnetic Radiation

A form of energy that exhibits wavelike behavior as it travels through space.

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Electromagnetic Spectrum

All the forms of electromagnetic radiation.

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Same

Do the forms of electromagnetic radiation move at the same speed or a different speed through a vacuum?

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Wavelength

The distance between corresponding points on adjacent waves.

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Frequency

The number of waves that pass a given point in a specific time, usually one second.

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Hertz

Unit used to express frequency.

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Inversely Proportional

Wavelength and Frequency are _____________ ____________.

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Photoelectric Effect

Refers to the emission of electrons from a metal when light shines on the metal.

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Frequency

Light’s ____________ needs to reach a certain minimum in order to emit electrons from a certain metal.

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Max Planck

German physicist who explained the photoelectric effect after studying the emission of electrons by hot objects.

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Quantum

The minimum quantity of energy that can be lost or gained from an atom.

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Albert Einstein

German physicist who suggested that electromagnetic radiation had a dual wave-particle nature, and that it is absorbed by matter in only whole numbers of photons.

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Photon

Particle of electromagnetic radiation having zero mass and carrying a quantum of energy.

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Ground State

The lowest energy state of an atom; only one for atoms of a given element.

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Excited State

A state in which an atom has a higher potential energy than it has in its ground state; there are many possible, each with a unique energy.

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Released

Energy is ___________ in the form of electromagnetic radiation when an atom returns to a ground state or a lower energy state from an excited state.

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Emission-Line Spectrum

When a narrow beam of emitted light is shined through a prism, it is separated into specific colors of the visible spectrum; these bands of light make up an element’s [this].

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Continuous Spectrum

The emission of a continuous range of frequencies of electromagnetic radiation.

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Quantum Theory

Atomic theory that attempted to explain why the hydrogen atoms only gave off specific frequencies of light.

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Equal

The energy of the photon released is _________ to the difference in energy between the atom’s initial state and its final state.

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Orbits

Paths that the electron can circle the nucleus on as part of Bohr’s model of the hydrogen atom.

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Increases

The energy of an electron ___________ as it moves farther away from the nucleus.

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Gaining

An electron can move to a higher-energy orbit by __________ an amount of energy equal to the difference in energy between the desired and initial orbit.

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Emission

Process by which an electron falls to a lower energy level and releases a photon.

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Absorption

Process by which energy is added to an atom in order to move an electron from a lower energy level to a higher energy level.

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Louis de Broglie

Scientist who suggested that electrons have a dual wave-particle nature; suggested that electrons be considered waves confined to the space around an atomic nucleus.

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Diffraction

The bending of a wave as it passes by the edge of an object or through a small opening.

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Interference

Occurs when waves overlap, resulting in a reduction of energy in same areas and an increase in energy in others.

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Heisenberg Uncertainty Principle

States that it is impossible to determine simultaneously both the position and velocity of an electron or any other particle.

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Erwin Schrödinger

Used the hypothesis that electrons have a dual wave-particle nature to develop an equation that treated electrons in atoms as waves; quantization of electron energies was a natural outcome of said equation.

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Quantum Theory

Describes mathematically the wave properties of electrons and other very small particles.

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Wave Functions

Solutions to the Schrödinger wave equation.

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Orbital

A three-dimensional region around the nucleus that indicates the probable location of an electron.

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Quantum Numbers

Specify the properties of atomic orbitals and the properties of electrons in orbitals.

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Principal Quantum Number

Symbolized by n, indicates the main energy level occupied by the electron. Values of n are positive integers only.

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Increases

As n increases, the electron’s energy and its average distance from the nucleus ____________.

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Angular Momentum Quantum Number

Symbolized by l, and indicates the shape of the orbital. The values of l allowed are 0 and all positive integers less than or equal to n-1.

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S

Spherical orbitals; l=0.

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P

Dumbbell-shaped orbitals; l=1.

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D

Complex orbitals; l=2.

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F

More complex orbitals; l=3.

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N

In the nth main energy level, there are __ sublevels.

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Magnetic Quantum Number

Symbolized by m, and indicates the orientation of an orbital around the nucleus. The m values are whole numbers (including 0) from -l to +l.

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Spin Quantum Number

Has only two possible values—+1/2 and -1/2—which indicate the two fundamental spin states of an electron in an orbital.

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Electron Configuration

The arrangement of electrons in an atom.

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Ground State Electron Configuration

The lowest-energy arrangement of the electrons for each element.

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Aufbau Principle

An electron occupies the lowest-energy orbital that can receive it.

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Pauli Exclusion Principle

No two electrons in the same atom can have the same set of four quantum numbers.

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Hund’s Rule

Orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron, and all electrons in singly occupied orbitals must have the same spin state.

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Highest-Occupied Energy Level

The electron-containing main energy level with the highest principle quantum number

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Inner-Shell Electrons

Electrons that are not in the highest-occupied energy level.

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Octet

Atoms which have the s and p sublevels of their highest-occupied energy level are said to have an _______ of electrons.

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Noble Gases

The elements in Group 18; includes Helium, Neon, Argon, Krypton, Xenon, and Radon

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Noble Gas Configuration

Refers to an outer main energy level occupied, in most cases, by eight electrons.

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