General Chemistry II Final Exam

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Always Soluble

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1

Always Soluble

All group I cations

NH₄⁺

Nitrates (NO₃⁻)

Acetates (CH₃CO₂⁻)

Perchlorates and Chlorates (ClO₄⁻, ClO₃⁻)

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2

Usually Insoluble

Hydroxides (OH⁻)

Phosphates (PO₄³⁻)

Carbonates (CO₃²⁻)

Sulfides (S²⁻)

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3

Hydroxide

OH⁻

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4

Peroxide

O₂²⁻

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5

Cyanide

CN⁻

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6

Carbonate

CO₃²⁻

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7

Hydrogen Carbonate (Bicarbonate)

HCO₃⁻

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8

Acetate

CH₃CO₂⁻

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9

Nitrate

NO₃⁻

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10

Nitrite

NO₂⁻

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11

Ammonium

NH₄⁺

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12

Perchlorate

ClO₄⁻

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13

Chlorate

ClO₃⁻

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14

Chlorite

ClO₂⁻

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15

Hypochlorite

ClO⁻

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16

Sulfate

SO₄²⁻

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17

Sulfite

SO₃²⁻

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18

Hydrogen Sulfate

HSO₄⁻

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19

Hydrogen Sulfite

HSO₃⁻

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20

Permanganate

MnO₄⁻

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21

Dichromate

Cr₂O₇²⁻

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22

Chromate

CrO₄²⁻

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23

Phosphate

PO₄³⁻

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24

Phosphite

PO₃³⁻

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25

Hydrogen Phosphate

HPO₄²⁻

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26

Hydrogen Phosphite

HPO₃²⁻

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27

Dihydrogen Phosphite

H₂PO₃⁻

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28

The Six Strong Acids

Hydrochloric Acid, Hydrobromic Acid, Hydroiodic Acid, Nitric Acid, Perchloric Acid, and Sulfuric Acid

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Hydrochloric Acid

HCl (aq)

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30

Hydrobromic Acid

HBr (aq)

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31

Hydroiodic Acid

HI (aq)

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32

Nitric Acid

HNO₃ (aq)

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33

Perchloric Acid

HClO₄ (aq)

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34

Sulfuric Acid

H₂SO₄ (aq)

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35

Chemical Equilibrium

a state of dynamic equilibrium in which the rate of the forward reaction and the rate of the reverse reaction are equal

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36

Law of Mass Action

describes equilibrium condition

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37

Large K Values

the equilibrium favors the products

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38

Small K Values

the equilibrium favors the reactants

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39

LeChatelier's Principle

when stress is applied to a system at equilibrium, the system will respond by relieving the stress

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40

Exothermic Reaction

heat is a product

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41

Endothermic Reaction

heat is a reactant

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42

Common Ion Effect/Salt Effect

an equilibrium will shift if a common ion is added to the solution

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43

Q > K

too many products, favor reverse reaction

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Q < K

too many reactants, favor forward reaction

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Q = K

reaction is at equilibrium

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46

Acid

proton donor, proton must be bound to a highly electronegative element

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Base

proton acceptor

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Amphoteric

substance that can react as an acid or a base

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49

Strong Acids

100% dissociation of acidic protons

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50

Weak Acids

less than 100% acid dissociation

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51

Strong Bases

100% base hydrolysis in water

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52

Weak Bases

less than 100% base molecules/ions accept protons

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53

Leveling Effect

limits the acid strength of solutes in a particular solvent

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54

Buffer Solutions

weak acid/weak base conjugate pair that resists pH change

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Buffer Capacity

the amount of acid/base that a buffer system can resist before pH starts to change rapidly

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Titration Equivalence Point

point where the reaction ended

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57

Titration End Point

point where the indicator changes color

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58

Intramolecular Forces

forces holding a molecule together

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59

Intermolecular Forces

forces holding molecules or aggregates of ions/atoms together

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60

Polar Molecules

asymmetrical molecules that have an electronegativity difference greater than or equal to 0.5

these molecules form dilpoles

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61

The Intermolecular Forces From Strongest to Weakest

Ionic Forces > Hydrogen Bonding > Dipoles > London Forces

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London Dispersion Forces

weak temporarily induced dipoles

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The Relationship Between Intermolecular Forces and Surface Tension

the stronger the intermolecular forces, the stronger the surface tension

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Cohesive Force

attraction within the substance/mixture

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Adhesive Force

attraction between different substances

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Viscosity

resistance to flow

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The Relationship Between Intermolecular Forces and Viscosity

the stronger the intermolecular forces, the higher the viscosity

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68

The Equation for Calculating Heat if Temperature is Changing

Q = mC∆T

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The Equation for Calculating Heat When There is a Change in State

Q = m∆H

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70

Solvent

the majority compound

there can only be one in the any solution

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71

Solute

the minority compound

there can be many

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72

Electrolytes

compounds which generate ions when dissolved in water

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Strong Electrolyte

100% of the formula units dissolve into ions

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Weak Electrolytes

less than 100% of the formula units dissociate into ions

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Non-Electrolyte

no ions are formed when dissolved in water

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Entropy (S)

the amount of disorder in a system

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Soluble Compound

more than 0.02 moles of compound can dissolve in 1.0 L of water

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Insoluble Compound

less than 0.02 moles of compound can dissolve in 1.0 L of water

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Saturated Solution

solution contains maximum amount of solute possible

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80

Supersaturated Solution

a solution that is carefully prepared with a concentration that exceeds its solubility

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Miscibility

liquid-liquid solubility

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82

Miscible Liquids

liquids mix to form a solution

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Immiscible Liquids

liquids that do not mix

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Colloids

consists of solute particles distributed throughout a solution

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85

Henry’s Law

the amount of gas that can be dissolved in a liquid is directly proportional to the partial pressure of the gas above the liquid

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Vapor Pressure

pressure of evaporated molecules above a liquid

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Molality

moles of solute per kilogram of solvent

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Mole Fraction

the ratio of a solute’s molar amount to the total number of moles of all solution components

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Colligative Properties

properties that depend on the concentration of the solute and not the identity of the solute

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90

Raoult’s Law

a solution has a lower vapor pressure than that of a pure solvent

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Dalton’s Law

the overall pressure of a gas is the sum of the partial pressures of its components

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Osmotic Pressure

the pressure that must be applied to prevent the net movement of water from the solvent to the solution of higher concentration

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93

Hypotonic Solution

external concentration lower than internal concentration

water flows into cell

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Hypertonic Solution

external concentration higher than internal concentration

water flows out of cell

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Isotonic Solution

external and internal concentrations are equal

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96

Thermodynamics

determines the spontaneity of a chemical reaction

the study of energy, work, and heat

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Spontaneous

reaction proceeds in direction written

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98

Nonspontaneous

reaction does not proceed in direction written

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99

Kinetics

determines that rate at which the reaction proceeds

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100

Activation Energy

energy of collision needed to initiate a reaction

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