Unit 4; Chemical Bonding and Structure

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Ionic Bonding

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1

Ionic Bonding

Electrostatic attraction between oppositely charged ions.

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2

Physical Properties

  • High boiling and melting point bc strong electrostatic attraction

  • Low electrical conductivity when solid bc ions are held in a fixed position

  • Brittle & shatter when layers of ions are incorrectly aligned

  • High solubility bc water molecules are attracted to the oppositely charged ions

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3

Covalent Bonding

The electrostatic attraction between positively charged nuclei and shared pairs of bonding electrons.

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4

Types of covalent bonds

  • EN 0.5-1.7 = Polar Covalent

  • EN 0.1-0.4 = Non-Polar Covalent

  • EN 0 = Pure Covalent

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5

Molecular Polarity

If a molecule is symmetrical, it is non-polar no matter the types of bonds.

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6

London Dispersion Forces

  • Weakest

  • Between all atoms and molecules

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7

Dipole-Dipole

  • Only between polar molecules

  • Caused by the difference in electronegativity

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8

Hydrogen Bond

  • Molecules that have a nitrogen, oxygen or fluorine atom directly bonded to a hydrogen atom.

  • Strongest

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9

Metallic Bonding

  • Occurs in all directions between the positive ions and delocalized electrons within the lattice structure.

  • Malleable bc the layers of metal ion slide over each other without breaking the bonds

  • Delocalized electrons conduct heat and make for a high electrical conductivity.

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10

Alloys

Homogeneous mixtures composed of two or more metals or a metal and a non-metal. Often stronger and more resistant to corrosion than their component elements.

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